Mourinho, who has won the Champions League, Europa League and the UEFA Cup, now has the chance to win the inaugural third-tier European title and Roma's first trophy in 14 years
Schalke 04 hit back from two goals down to draw 2-2 and overcome fellow Germans Borussia Moenchenglach on away goals in their Europa League last 16 tie while Manchester United edged Rostov 1-0 to progress on Thursday.
Champions Manchester City's 12-match winning streak in the Premier League came to an end as Julio Enciso's stunner earned sixth-placed Brighton and Hove Albion a 1-1 draw.
Holders Manchester City will take on RB Leipzig, Red Star Belgrade and Young Boys in Group G.
Images from UEFA Champions League matches played on Wednesday.
Jim Ratcliffe pledged to invest $300 million in Manchester United to try to revive its fortunes.
Inter Milan's aversion to Europa League football continued with a 3-1 defeat at Sparta Prague, while AS Roma ended a continental hoodoo stretching back seven games with a 4-0 home win over Romanian side FC Astra on Thursday.
'I think that the only thing that we lacked was to convert the chances. We were good in the high press. After going behind, we generated 20 chances and six or seven were very clear.'
Frappart was also the first woman to officiate a men's Champions League game in 2020.
La Liga leaders Real Madrid cruised to a 4-0 home win over relegation-threatened Celta Vigo on Sunday to restore their seven-point lead at the top of the table with a dominant display.
David De Gea has left Manchester United following the end of his contract after 12 seasons with the Old Trafford side.
Leaders Barcelona played out a second straight 0-0 draw in LaLiga after mid-table Getafe battled for a home point in a hard-fought game on Sunday.
Manchester United bounced back from their defeat with a 4-1 win over Real Betis in the first leg of their Europa League last-16 tie.
;You will have setbacks. We beat Arsenal, we beat Liverpool. On Sunday, we had a bad day at the office. City were better, we have to accept that. But we can't accept our unacceptable performance. So thank you for the lesson, Pep and City. We have to understand, we have to do things much better.'
The world of sport reacted to the death of Queen Elizabeth on Thursday with a raft of cancellations across cricket, golf, rugby and cycling, while others paid tribute by holding a minute's silence.
Manchester City held their nerve to beat Sevilla 5-4 on penalties
Kevin de Bruyne struck twice to inspire Manchester City to a dominant 4-2 win at Crystal Palace on Saturday and move the champions level on points with Liverpool at the top of the Premier League table.
Paul Pogba repaid some of his world record transfer fee with two goals as Manchester United rediscovered their early-season shine, cruising to a 4-1 Europa League win over Fenerbahce to go top of their group on Thursday. Pogba scored a penalty and rifled United's third into the top corner. Anthony Martial also netted from the spot and Jesse Lingard fired home in the second half before former Old Trafford favourite Robin van Persie pulled one back for Fenerbahce. Inter Milan and AS Roma, though, had more testing evenings. Coach Frank de Boer breathed a sigh of relief when Inter survived an onslaught from Southampton to end a three-match losing streak with a 1-0 victory while Roma conceded twice late on to draw 3-3 at home to Austria Vienna.
Aston Villa claimed their first three points of the Premier League Season
The value of an in-form striker was underlined as Tottenham Hotspur, Liverpool and Athletic Bilbao needed goals from pivotal front men to grab vital wins that booked places in the Europa League last 32 on Thursday.
Barcelona have won the Champions League five times, most recently in 2015, and face a tough task to get back to the top table of European football after being forced to sell club legend Lionel Messi due to financial problems.
Manchester City clinched the Champions League title to seal their treble in a sensational season.
Russia's bid to host the Euro 2028 or the Euro 2032 tournaments have also been declared ineligible, the Switzerland-based governing body said.
A round-up of Tuesday's action in the UEFA Champions League.
Barcelona fought back to earn a 2-2 draw with Manchester United in a pulsating Europa League knockout round playoff first leg on Thursday.
A summary of Sunday's action in the English Premier League.
Athletic Bilbao beat Barcelona 4-2 at home to knock them out of the Copa del Rey
Manchester United climbed to third place in their quest for a berth in next season's Champions League.
A summary of Thursday's second leg quarter-final matches in the Europa League.
The three Premier League and three La Liga clubs in the last eight avoided each other, with Manchester City up against Atletico Madrid and Liverpool to face Portuguese side Benfica.
Manchester United crushed Newcastle United's hopes of a claiming a first domestic trophy for nearly 70 years with a clinical 2-0 victory in the League Cup final at Wembley on Sunday.
Images from Sunday's action in the Premier League
With Crystal Palace dangerously close to being relegated, manager Patrick Vieira was sacked after 20 months in charge.
Marcus Rashford has made more appearances than any other player at the club this season
News of all that's transpired on and off the football field
Bayern expect a top performance against Manchester United, says Tuchel
Barcelona were held 1-1 at home by Napoli in the first leg of their Europa League knockout stage playoff
Saka double against Palace sends Arsenal eight points clear
IMAGES from the Champions League matches played on Tuesday.
UEFA announces UCL final hosts for next four seasons.